Dipole moments of some selenophosphoryl compounds

Authors :: I. A. Nuretdinov
I. I. Vandyukova
R. R. Shagidullin
Source :: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 27:1225-1227
Publication Year :: 1978
Publisher :: Springer Science and Business Media LLC, 1978.
Abstract: 1. The molecular dipole moments (DM) of the 26 studied selenophosphoryl compounds vary in the range 2.70–6.65 D. The reasons for the changes in the DM are discussed. 2. The dipole moments of the P=Se bond displays a greater variability than do P=S and P=O. According to the obtained and literature data, the polarizability and coordination character of the P=X bond changes in the order: P=Se> P=Se> P=O.

Subjects :: Crystallography
Dipole
Chemistry
Polarizability
Computational chemistry
General Chemistry

ISSN :: 15739171 and 05685230
Volume :: 27
Database :: OpenAIRE
Journal :: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Accession number :: edsair.doi...........9aeef3beae3f8ce07e53dcd1656737d4
Full Text :: https://doi.org/10.1007/bf00923384