ChemInform Abstract: A Sustainable Procedure for Highly Enantioselective Organocatalyzed Diels-Alder Cycloadditions in Homogeneous Ionic Liquid/Water Phase

Authors :: Antonio De Nino
A. Garofalo
Beatrice Russo
Olga Bortolini
Giovanni Sindona
Loredana Maiuolo
Source :: ChemInform. 42
Publication Year :: 2011
Publisher :: Wiley, 2011.
Abstract: The MacMillan iminium catalyst was investigated for asymmetric Diels–Alder cycloadditions in ionic liquid/H2O homogeneous phase. Superior selectivity, product yield, and shorter reaction times were observed in comparison with classical organic solvents. Additional advantages are the easy synthetic procedure, the excellent recovery of products, and the recyclability of the whole system.

Subjects :: chemistry.chemical_classification
chemistry.chemical_compound
chemistry
Yield (chemistry)
Phase (matter)
Ionic liquid
Enantioselective synthesis
Organic chemistry
Iminium
General Medicine
Bridged compounds
Selectivity
Catalysis

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