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Reactivity of 1,1′-thiocarbonyldiimidazole with glycosides: a novel and efficient glycosidic activation
- Source :
- Tetrahedron Letters. 43:241-244
- Publication Year :
- 2002
- Publisher :
- Elsevier BV, 2002.
-
Abstract
- The synthesis of monoglycosyl imidazoles and 1,1′-di- O -glycosides is described by direct glycosylation process from reducing sugar in the presence of 1,1′-thiocarbonyldiimidazole. Novel anomeric groups as 1- O -(imidazolyl)thiocarbonyl and 1- O -(imidazolyl)carbonyl are presented as potent glycosidic activators.
Details
- ISSN :
- 00404039
- Volume :
- 43
- Database :
- OpenAIRE
- Journal :
- Tetrahedron Letters
- Accession number :
- edsair.doi...........9abde1819800fe428487a3e0c36ad983