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Trapping of a Pseudotetrahedral CoIIO4 Core in Mixed-Valence Mixed-Geometry [Co5] Coordination Aggregates: Synthetic Marvel, Structures, and Magnetism

Authors :
Gopalan Rajaraman
Krishna Chattopadhyay
Arup Sarkar
Mark Murrie
María José Heras Ojea
Debashis Ray
Source :
Inorganic Chemistry. 57:13176-13187
Publication Year :
2018
Publisher :
American Chemical Society (ACS), 2018.

Abstract

A systematic one-step one-pot multicomponent reaction of Co(ClO4)2·6H2O, H3L (2,6-bis((2-(2-hydroxyethylamino)ethylimino)methyl)-4-methylphenol), and readily available carboxylate salts (RCO2Na; R ...

Details

ISSN :
1520510X and 00201669
Volume :
57
Database :
OpenAIRE
Journal :
Inorganic Chemistry
Accession number :
edsair.doi...........99d79c9fe936479cbd8a3d9cabe2000c