Complexes of cuprous phenylacetylenide with phosphorous acid amides

Authors :: M. Yu. Antipin
L. K. Vasyanina
Yu. T. Struchkov
I. R. Gol'ding
Yu. I. Blokhin
E. E. Nifant'ev
Source :: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 39:160-164
Publication Year :: 1990
Publisher :: Springer Science and Business Media LLC, 1990.
Abstract: Complexes of cuprous phenylacetylenide (CPA) were obtained with various amides of phosphorous acid, which are cubane-like tetramers (PhC=CCuL)4. Copper is coordinated at the phosphorus atom in these complexes. The coordination shift of the ligands in the31P NMR spectra are directly dependent on the electronegativity of the heteroatoms at phosphorus.

Subjects :: Electronegativity
NMR spectra database
chemistry.chemical_compound
chemistry
Phosphorus
Phosphorus atom
Inorganic chemistry
Heteroatom
chemistry.chemical_element
General Chemistry
Phosphorous acid
Copper

ISSN :: 15739171 and 05685230
Volume :: 39
Database :: OpenAIRE
Journal :: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Accession number :: edsair.doi...........99cc43b16461e8565abf16f9266ab5d3
Full Text :: https://doi.org/10.1007/bf00963023