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Rate-limiting NO+ formation in nitrosation reaction in acetonitrile
- Source :
- Journal of the Chemical Society, Chemical Communications. :571
- Publication Year :
- 1988
- Publisher :
- Royal Society of Chemistry (RSC), 1988.
-
Abstract
- Acid-catalysed nitrosation of methanol, thioglycolic acid, and water in acetonitrile using alkyl nitrites or nitrous acid (except in the case of water), is kinetically zero order in the substrate, consistent with rate-limiting NO+ formation.
Details
- ISSN :
- 00224936
- Database :
- OpenAIRE
- Journal :
- Journal of the Chemical Society, Chemical Communications
- Accession number :
- edsair.doi...........99cb41fd468ff44989068d5e289bc509
- Full Text :
- https://doi.org/10.1039/c39880000571