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Palladium Nanoparticles Suspended in an Ionic Liquid as Reusable Catalyst for Alkyne Semihydrogenation
- Source :
- Bulletin of the Korean Chemical Society. 31:2195-2200
- Publication Year :
- 2010
- Publisher :
- Korean Chemical Society, 2010.
-
Abstract
- The reaction of PdCl 2 dispersed in tetra-n-butylammonium bromide with tributyl amine at 120 °C under argon leads to stable isolable nanometric particles. X-ray diffraction analysis of the material indicated that it is constituted of Pd(0). Transmission electron microscopy analysis of the particles dispersed in acetone shows the mean particle size distribution (4 ± 1 nm). The isolated palladium nanoparticles can be dispersed in an ionic liquid or in methanol or used in solventless condition for selective hydrogenation of 2-hexyne under mild reaction conditions(0.2 MPa and 20 °C). The commercial variety of the Lindlar catalyst was also studied for comparative investigations.
Details
- ISSN :
- 02532964
- Volume :
- 31
- Database :
- OpenAIRE
- Journal :
- Bulletin of the Korean Chemical Society
- Accession number :
- edsair.doi...........9991464b6dab21429b2d2feb2fa9723e