Composition and size of Martian aerosols as seen in the IR from solar occultation measurements by NOMAD onboard TGO

IntroductionThe nature, size and content of aerosols in the atmosphere affect the energy budget on all planets, hence the atmospheric dynamic of the planet. Mars exhibits three types of atmospheric aerosol. Mineral dust, water ice and carbon dioxide ice. Martian aerosols nature and size distribution were observed using many different methods and experiments, from rovers to satellites. Exhaustive review scan be found in [1] and in [2]. Usually, dust effective radius, reff, ranges from 1 to 2 μm and its effective variance, νeff, from 0.2 to 0.4. H2O ice reff ranges from 1 to 5 μm and its νeff from 0.1 to 0.4. However, these two parameters and their variability are poorly constraint in the vertical to date. ExoMars TGO mission (ESA/Roscosmos) was primarily designed to study trace gases, thermal structure and aerosol content in Mars atmosphere with unprecedented vertical resolution [3]. NOMAD-SO Data processingNOMAD (Nadir and Occultation for MArs Discovery) is suite of two infrared spectrometers onboard the ExoMars 2016 Trace Gas Orbiter (TGO) orbiter, covering the spectral range of 0.2 to 4.3 μm [4]. An Acousto-Optical Tunable Filter (AOTF) is used to select different spectral windows. The sampling of this channel is approximately of 1 second, allowing a vertical sampling about 1km. the SO channel is able to observe the atmosphere at a given altitude with 6 different diffraction orders. For this study, we selected a configuration of 5 diffraction orders (121,134,149,168,190) effectively spanning the overall spectral range of NOMAD.In order to evaluate the local extinction due to aerosols, we use an inversion program called Retrieval Control Program (RCP). It is a multi-parameter non-linear least squares fitting of measured and modelled spectra [5]. Its forward model, KOPRA, was recently adapted to limb emissions on Mars [6] and for solar occultation data on Mars for the first time. RCP solves iteratively the inverse problem [7] and is described in details in [8]. The regularization matrix is build from Tikhonov-type terms of different orders which can be combined to obtain a custom-tailored regularization for any particular retrieval problem.An example of the retrieved extinction profile is shown in Fig 1. The retrieved extinctions differs from previous work on aerosols using ACS data [9,10] using the Onion-peeling or Abel's transform method since this global fit is less affected by the large error propagation to low altitudes typical of those methods, and the lower Martian atmosphere is precisely where aerosols are particular relevant.Fig 1.Mean extinction cross-section ratio modellingIn order to model the optical behavior of the Martian aerosol we chose the log-normal distribution which is widely used in atmospheric sciences. It is a function of two parameters (rg, σg). In optics, we change those parameters to more suitable ones, the effective radius, reff and its corresponding effective variance νeff. For any aerosol size distribution, the extinction k is km-1 is k(λ) = N . σext (λreff,νeff). N is the aerosol number density and σext (λ,reff,νeff) is the mean average extinction cross-section at a wavelength λ, a specific aerosol distribution defined by (reff,νeff). We build a look-up table of dust and water ice σext at the selected NOMAD order's wavelengths for different sets of (reff,νeff). The extinction are evaluated with a Lorenz-Mie code for polydisperse spherical particle from [11].Aerosol composition and size distribution evaluationWe will detail the process of evaluating the aerosol composition and size distribution that consists of a mix of non-linear least square and brute force in order to evaluate the best set of parameters (reff,νeff ,γ) where γ represent a mixture of dust and H2O ice. The NLSQ algorithm is provided by the SciPy Python package [12]. To assess the robustness and limitations of our evaluation procedure, we will present results against synthetic extinction signal. We will discuss our main results, especially for the period covering the Global Dust Storm of MY34 (Fig 2.).Fig 2.AcknowledgmentsThe IAA/CSIC team acknowledges financial support from the State Agency for Research of the Spanish MCIU through the \emph{"Center of Excellence Severo Ochoa"} award for the Instituto de Astrofísica de Andalucía (SEV-2017-0709) and funding by grant PGC2018-101836-B-100 (MCIU/AEI/FEDER, EU). ExoMars is a space mission of the European Space Agency (ESA) and Roscosmos. The NOMAD experiment is led by the Royal Belgian Institute for Space Aeronomy (IASB-BIRA), assisted by Co-PI teams from Spain (IAA-CSIC), Italy (INAF-IAPS), and the United Kingdom (Open University).References[1] Robert M. Haberle et al., eds. The Atmosphere and Climate of Mars. 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