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Microstructural Evolution of Lead-Free Solder Joints in Ultrasonic-Assisted Soldering
- Source :
- Journal of Electronic Materials. 45:88-97
- Publication Year :
- 2015
- Publisher :
- Springer Science and Business Media LLC, 2015.
-
Abstract
- Solder joint reliability greatly depends on the microstructure of the solder matrix and the morphology of intermetallic compounds (IMCs) in the joints. Addition of strengthening phases such as carbon nanotubes and ceramic particles to solder joints to improve their properties has been widely studied. In this work, ultrasonic vibration (USV) of casting ingots was applied to considerably improve their microstructure and properties, and the resulting influence on fluxless soldering of Cu/Sn-3.0Ag-0.5Cu/Cu joints and their microstructural evolution was investigated. It was demonstrated that USV application during reflow of Sn-based solder had favorable effects on β-Sn grain size refinement as well as the growth and distribution of various IMC phases within the joints. The β-Sn grain size was significantly refined as the ultrasound power was increased, with a reduction of almost 90% from more than 100 μm to below 10 μm. Long and large Cu6Sn5 tubes in the solder matrix of the joints were broken into tiny ones. Needle-shaped Ag3Sn was transformed into flake-shaped. These IMCs were mainly precipitated along β-Sn phase boundaries. High-temperature storage tests indicated that the growth rate of interfacial IMCs in joints formed with USV was slower than in conventional reflow joints. The mechanisms of grain refinement and IMC fragmentation are discussed and related to the ultrasonic effects.
- Subjects :
- 010302 applied physics
Microstructural evolution
Materials science
Metallurgy
Intermetallic
02 engineering and technology
Carbon nanotube
021001 nanoscience & nanotechnology
Condensed Matter Physics
Microstructure
01 natural sciences
Grain size
Electronic, Optical and Magnetic Materials
law.invention
law
Soldering
visual_art
0103 physical sciences
Materials Chemistry
visual_art.visual_art_medium
Ultrasonic sensor
Ceramic
Electrical and Electronic Engineering
0210 nano-technology
Subjects
Details
- ISSN :
- 1543186X and 03615235
- Volume :
- 45
- Database :
- OpenAIRE
- Journal :
- Journal of Electronic Materials
- Accession number :
- edsair.doi...........98dc1b30359266ed4ca86f18bb9af226