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The sigmatropic rearrangements of 2-oxyanilinium ylides

Authors :
W. David Ollis
Ian O. Sutherland
Yodhathai Thebtaranonth
Source :
Journal of the Chemical Society, Chemical Communications. :653
Publication Year :
1973
Publisher :
Royal Society of Chemistry (RSC), 1973.

Abstract

The [1,4] sigmatropic rearrangement of the anilinium ylides derived from the salts (1) is an intramolecular process, (1)→(2); the N-allyl ylide (8) reacts, in addition, by a sequence of [2,3] and [3,3] sigmatropic rearrangements to give the allyl phenol (10).

Details

ISSN :
00224936
Database :
OpenAIRE
Journal :
Journal of the Chemical Society, Chemical Communications
Accession number :
edsair.doi...........975532fb49275001637950617b0b7d14
Full Text :
https://doi.org/10.1039/c39730000653