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On the relative accuracies of eigenvalue bounds

Authors :
P J Haskins
C A Coulson
Source :
Journal of Physics B: Atomic and Molecular Physics. 6:1741-1750
Publication Year :
1973
Publisher :
IOP Publishing, 1973.

Abstract

The authors examine the relative accuracies of the Rayleigh upper bound and the Temple (1928), Weinstein (1934) and Stevenson (1938) lower bounds in the limit of an accurate trial function. This analysis leads to an understanding of why lower bounds have usually been observed to have larger errors than upper bounds using the same trial function. In the second part a simple relationship is given between the errors in classical lower bounds, and intermediate- operator lower bounds. The relative errors of Rayleigh and intermediate-operator methods are examined in the limit of an accurate trial function.

Details

ISSN :
00223700
Volume :
6
Database :
OpenAIRE
Journal :
Journal of Physics B: Atomic and Molecular Physics
Accession number :
edsair.doi...........96611069b6694f2c00e58f1b31fc5aec
Full Text :
https://doi.org/10.1088/0022-3700/6/9/017