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Di-μ-hydroxo-bis[(N,N,N′,N′-tetramethylethylenediamine)copper(II)] dichloride from X-ray powder data

Authors :
Vladimir V. Chernyshev
Dmitry V. Albov
Dmitry V. Davydov
Source :
Acta Crystallographica Section E Structure Reports Online. 60:m1193-m1195
Publication Year :
2004
Publisher :
International Union of Crystallography (IUCr), 2004.

Abstract

The crystal structure of the title complex, [Cu2(OH)2(TMEDA)2]Cl2 (TMEDA is N,N,N′,N′-tetra­methyl­ethyl­ene­di­amine, C6H16N2), has been characterized by X-ray powder diffraction. The cation is a binuclear complex with a Cu⋯Cu distance of 3.031 (7) A and occupies a special position of 222 symmetry, while the chloride anions are on a twofold axis. There is a hydrogen bond linking a bridging hydroxy group with the anion [O⋯Cl = 2.993 (14) A].

Details

ISSN :
16005368
Volume :
60
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E Structure Reports Online
Accession number :
edsair.doi...........960b640f0d3759958ea20668dba51bd7
Full Text :
https://doi.org/10.1107/s1600536804018264