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Di-μ-hydroxo-bis[(N,N,N′,N′-tetramethylethylenediamine)copper(II)] dichloride from X-ray powder data
- Source :
- Acta Crystallographica Section E Structure Reports Online. 60:m1193-m1195
- Publication Year :
- 2004
- Publisher :
- International Union of Crystallography (IUCr), 2004.
-
Abstract
- The crystal structure of the title complex, [Cu2(OH)2(TMEDA)2]Cl2 (TMEDA is N,N,N′,N′-tetra­methyl­ethyl­ene­di­amine, C6H16N2), has been characterized by X-ray powder diffraction. The cation is a binuclear complex with a Cu⋯Cu distance of 3.031 (7) A and occupies a special position of 222 symmetry, while the chloride anions are on a twofold axis. There is a hydrogen bond linking a bridging hydroxy group with the anion [O⋯Cl = 2.993 (14) A].
- Subjects :
- biology
Chemistry
Hydrogen bond
Stereochemistry
chemistry.chemical_element
General Chemistry
Crystal structure
Condensed Matter Physics
biology.organism_classification
Chloride
Medicinal chemistry
Copper
medicine
Tetra
General Materials Science
Amine gas treating
Ene reaction
Powder diffraction
medicine.drug
Subjects
Details
- ISSN :
- 16005368
- Volume :
- 60
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section E Structure Reports Online
- Accession number :
- edsair.doi...........960b640f0d3759958ea20668dba51bd7
- Full Text :
- https://doi.org/10.1107/s1600536804018264