ChemInform Abstract: 1,4-ADDITION TO TETRACYCLONE. KINETIC VS. THERMODYNAMIC PRODUCT DISTRIBUTION

Authors :: Robert L. Eagan
Byron H. Arison
Michael A. Ogliaruso
James P. Springer
Source :: Chemischer Informationsdienst. 16
Publication Year :: 1985
Publisher :: Wiley, 1985.
Abstract: L'addition de Michael de CN − avec la tetracyclone conduit a un enolate, qui, protone, donne un melange de diastereoisomeres cis et trans de la cyano-4 tetraphenyl-2,3,4,5 cyclopentene-2one-1; les proportions dependent des conditions de temperature et du solvant

Subjects :: Solvent
chemistry.chemical_compound
Addition reaction
Nitrile
Chemistry
Michael reaction
Protonation
General Medicine
Medicinal chemistry
Enone
Isomerization
Product distribution

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