Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Allylation of Aldehydes with Allylic Carbonates

Authors :: Takuya Ishii
Hirohisa Ohmiya
Shigeo Yasuda
Shunsuke Takemoto
Source :: Bulletin of the Chemical Society of Japan. 92:937-940
Publication Year :: 2019
Publisher :: The Chemical Society of Japan, 2019.
Abstract: The synergistic merger of a thiazolium N-heterocyclic carbene (NHC) catalyst and a palladium–bisphosphine catalyst enabled the allylation of aldehyde acyl anions using allylic carbonates as electro...

Subjects :: chemistry.chemical_classification
Allylic rearrangement
010405 organic chemistry
chemistry.chemical_element
General Chemistry
010402 general chemistry
01 natural sciences
Aldehyde
0104 chemical sciences
Catalysis
chemistry.chemical_compound
chemistry
Organic chemistry
Synergistic catalysis
Carbene
Palladium

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