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Solvolytic hydroperoxide rearrangements IV. Selective rearrangement of spiro[5,2]octan-4-ol
- Source :
- Tetrahedron Letters. 28:131-134
- Publication Year :
- 1987
- Publisher :
- Elsevier BV, 1987.
-
Abstract
- Rearrangement of spiro[5,2]octan-4-ol, 1, in acidified THF-H2O2 is a selective process in which substitution occurs with retention of configuration and ring-expansion with inversion of the carbinyl center.
Details
- ISSN :
- 00404039
- Volume :
- 28
- Database :
- OpenAIRE
- Journal :
- Tetrahedron Letters
- Accession number :
- edsair.doi...........95131e246748d5315f1cc1728a23c4dc
- Full Text :
- https://doi.org/10.1016/s0040-4039(00)95667-3