ChemInform Abstract: A New Prenylation Method Using the Lithium Enolate of Prenal. Reaction with Aldehydes and α,β-Unsaturated Aldehydes

Authors :: Jacques Poirier
Jérôme Emile Georges Guillemont
Lucette Duhamel
P. Chabardes
Source :: ChemInform. 23
Publication Year :: 2010
Publisher :: Wiley, 2010.
Abstract: A γ-condensation of the enolate of prenal 1 is observed with aldehydes and α,β-unsaturated aldehydes. In this last case, a conjugate addition is obtained. Intermediate dihydropyrans 4 yield dienals 5 by hydrolysis.

Subjects :: Hydrolysis
Prenylation
Chemistry
Yield (chemistry)
chemistry.chemical_element
Organic chemistry
Lithium
General Medicine
Conjugate

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