Back to Search Start Over

Tetrakis(μ-N-acetyl-N-phenylglycinato)bis[(N-acetyl-N-phenylglycinato)(1,10-phenanthroline-κ2N,N′)lanthanum(III)] dihydrate

Authors :
Qing-Jun Shen
Ai-Yun Fu
D.-Q. Wang
Source :
Acta Crystallographica Section E Structure Reports Online. 60:m1346-m1348
Publication Year :
2004
Publisher :
International Union of Crystallography (IUCr), 2004.

Abstract

In the title complex, [La2(C10H10NO3)6(C12H8N2)2]·2H2O, the LaIII atoms are bridged by two terdentate and two bidentate carboxyl­ate groups with an inversion centre between the two LaIII ions. Each La atom is nine-coordinated by two N atoms of 1,10-phenanthroline and seven O atoms belonging to N-acetyl-N-phenyl­glycine mol­ecules, and exhibits distorted tricapped trigonal prismatic geometry. The crystal structure is stabilized by intermolecular O—H⋯O hydrogen bonds.

Details

ISSN :
16005368
Volume :
60
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E Structure Reports Online
Accession number :
edsair.doi...........9328c982449ca10cb5401a55a0bc750f