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Niobium doping of Li1.2Mn0.54Ni0.13Co0.13O2 cathode materials with enhanced structural stability and electrochemical performance
- Source :
- Ceramics International. 46:23773-23779
- Publication Year :
- 2020
- Publisher :
- Elsevier BV, 2020.
-
Abstract
- Lithium-rich layered oxides with high energy density have been intensively investigated as advanced lithium-ion batteries cathode materials. However, capacity degradation and voltage decay caused by irreversible lattice oxygen loss and structural transformation during cycling restrict their application. Herein, we proposed a high valance cations Nb5+ doping strategy and synthesized a series of Li1.2Mn0.54-x/3Ni0.13-x/3Co0.13-x/3NbxO2 (x = 0, 0.01, 0.02 and 0.03) cathode materials. The effects of Nb5+ doping on crystallographic structure and electrochemical property were systematically studied. In virtue of the large ionic radii and strengthened Nb–O bonds, the doped samples present commendable structural stability and expanded interlayer spacing for Li-ions migration, which ensures the upgraded cyclic stability and rate performance. In particular, the electrode with x = 0.02 delivers a discharge specific capacity of 265.8 mAh g-1 at 0.2 C with decelerated voltage decay, while 86.9% capacity are remained after long-term cycles. Moreover, excellent discharge specific capacity of 153.4 mAh g−1 is still attained at 5 C accompanied with enhanced Li-ion diffusion kinetics.
- Subjects :
- 010302 applied physics
Materials science
Ionic radius
Process Chemistry and Technology
Doping
Niobium
chemistry.chemical_element
02 engineering and technology
Crystal structure
021001 nanoscience & nanotechnology
Electrochemistry
01 natural sciences
Cathode
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
law.invention
chemistry
Chemical engineering
law
Structural stability
0103 physical sciences
Electrode
Materials Chemistry
Ceramics and Composites
0210 nano-technology
Subjects
Details
- ISSN :
- 02728842
- Volume :
- 46
- Database :
- OpenAIRE
- Journal :
- Ceramics International
- Accession number :
- edsair.doi...........92946a619b273661b5d05b9b632d1f79