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UV-laser-assisted fluorination of polymers

Authors :
Frank Vollertsen
Carsten Wochnowski
S. Metev
K. Meteva
Source :
Materials Letters. 61:1046-1049
Publication Year :
2007
Publisher :
Elsevier BV, 2007.

Abstract

PMMA (Polymethylmethacrylate) substrate was covered with 1,2,3,5-tetrafluorobenzene by spin-coating. Then the sample was irradiated by a KrF-excimer laser ( λ = 248 nm). After drying out the polymeric substrate, the sample surface was investigated by SEM and EDX indicating some fluorine content at the top of the sample layer. A UV-photochemical fluorination mechanism is proposed.

Details

ISSN :
0167577X
Volume :
61
Database :
OpenAIRE
Journal :
Materials Letters
Accession number :
edsair.doi...........92408f86aaf85df0e6816f19d046638f
Full Text :
https://doi.org/10.1016/j.matlet.2006.06.054