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Structure and Magnetic Properties of A μ-Phenoxido-bridged Dinuclear Cobalt(II) Complex
- Source :
- Zeitschrift für anorganische und allgemeine Chemie. 637:720-723
- Publication Year :
- 2010
- Publisher :
- Wiley, 2010.
-
Abstract
- A new dinuclear cobalt(II) complex [Co(2)L(2)Cl(2)(CH(3)OH)(2)] (1), where HL = 3-[(furan-2-ylmethylimino) methyl]-2-hydroxy-5-methylbenzaldehyde, derived from the in situ condensation of 2,6-diformyl- 4-methylphenol with furfurylamine, was prepared and structurally and magnetically characterized. Single crystal X-ray structural determination reveals that the structure consists of centrosymmetric dinuclear units with each Co(II) ion in a slightly distorted octahedral environment. Lines' model, which in principle can theoretically separate in spin-only and orbital contribution, was used to fit the variable temperature susceptibility (2-300 K), suggesting an intramolecular antiferromagnetic interaction between the cobalt(II) ions.
Details
- ISSN :
- 00442313
- Volume :
- 637
- Database :
- OpenAIRE
- Journal :
- Zeitschrift für anorganische und allgemeine Chemie
- Accession number :
- edsair.doi...........8f052d0b94730be0c4f1c126adc3044f