ChemInform Abstract: Iridium-Catalyzed Asymmetric Hydrogenation of Imines in Supercritical Carbon Dioxide Using Phosphite-Type Ligands

Authors :: Elena S. Kelbysheva
Nikolay M. Loim
Eugenie A. Rastorguev
Sergey E. Lyubimov
Pavel V. Petrovskii
Vadim A. Davankov
Source :: ChemInform. 42
Publication Year :: 2011
Publisher :: Wiley, 2011.
Abstract: A series of chiral phosphite-type ligands has been evaluated in the iridium-catalyzed asymmetric hydrogenation of acyclic arylimines in supercritical CO 2 . High reactivities (100% conversion in 50–120 min) and enantioselectivities (up to 95%) were obtained.

Subjects :: Supercritical carbon dioxide
Chemistry
Asymmetric hydrogenation
chemistry.chemical_element
Organic chemistry
General Medicine
Iridium
Supercritical fluid
Catalysis

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