Ti-Doping to Reduce Conductivity in Bi0.85Nd0.15FeO3 Ceramics

In 2009, Karimi et al. reported that Bi1-xNdxFeO3 0.15 ≤ x ≤ 0.25 exhibited a PbZrO3 (PZ)-like structure. These authors presented some preliminary electrical data for the PZ-like composition but noted that the conductivity was too high to obtain radio-frequency measurements representative of the intrinsic properties. In this study, Bi0.85Nd0.15Fe1-yTiyO3 (0 ≤ y ≤ 0.1) were investigated, in which Ti acted as a donor dopant on the B-site. In contrast to the original study of Karimi et al., X-ray diffraction (XRD) of Bi0.85Nd0.15FeO3 revealed peaks which were attributed to a mixture of PZ-like and rhombohedral structures. However, as the Ti (0 0.3 to 1 eV. Plots of permittivity (ϵr) versus temperature for 0.01 ≤ y ≤ 0.05 revealed a step rather than a peak in ϵr on heating at the same temperature determined for the antiferroelectric–paraelectric phase transition by differential scanning calorimetry. Finally, large electric fields were applied to all doped samples which resulted in a linear dependence of polarisation on the electric field similar to that obtained for PbZrO3 ceramics under equivalent experimental conditions.