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A new face for bis(pyrazol-3-yl)pyridine: Incompatible geometric preferences dictates unprecedented pincer ligand connectivity
- Source :
- Inorganica Chimica Acta. 485:54-57
- Publication Year :
- 2019
- Publisher :
- Elsevier BV, 2019.
-
Abstract
- The planar pincer ligand bis(pyrazol-3-yl)pyridine, H2L, binds to copper(I) iodide to give a product of formula (H2L)2(CuI)3 which single crystal X-ray diffraction reveals to have two unprecedented features for this ligand: κ2 binding of one H2L and bridging of the second H2L across two copper centers. The broader implications of this finding are discussed.
- Subjects :
- chemistry.chemical_classification
010405 organic chemistry
Iodide
chemistry.chemical_element
010402 general chemistry
01 natural sciences
Copper
0104 chemical sciences
Inorganic Chemistry
Crystallography
chemistry.chemical_compound
chemistry
Pyridine
Materials Chemistry
Physical and Theoretical Chemistry
Pincer ligand
Single crystal
Subjects
Details
- ISSN :
- 00201693
- Volume :
- 485
- Database :
- OpenAIRE
- Journal :
- Inorganica Chimica Acta
- Accession number :
- edsair.doi...........8cd9fc212201d0d7ec374facc5c8ce94