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Purification of CO Based on Selenium-Amine-CO Chemistry
- Source :
- Bulletin of the Chemical Society of Japan. 67:2297-2300
- Publication Year :
- 1994
- Publisher :
- The Chemical Society of Japan, 1994.
-
Abstract
- Efficient separation of carbon monoxide from a binary mixture of carbon monoxide and hydrogen with selenium and secondary amines has been developed. The process consists of (i) selective reaction of CO with selenium and a secondary amine to form the corresponding ammonium carbamoselenoate 1 and (ii) thermolysis of 1 to form pure CO (99.9%) quantitatively. A Se–alcohol system is also usable but the results are inferior to that with a Se–amine system.
Details
- ISSN :
- 13480634 and 00092673
- Volume :
- 67
- Database :
- OpenAIRE
- Journal :
- Bulletin of the Chemical Society of Japan
- Accession number :
- edsair.doi...........8c8b6bfd152998842717df9db44a4dc0