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ChemInform Abstract: Kinetic v. Thermodynamic Effects During a Wolff-Kishner Reduction

Authors :
R. C. Schumann
Raymond M. Carman
Douglas J. Brecknell
Source :
ChemInform. 20
Publication Year :
1989
Publisher :
Wiley, 1989.

Abstract

A Wolff-Kishner reduction is discussed which leads to kinetic products through reduction of hydrazones derived from thermodynamically less-stable ketones of an equilibrium mixture. The syntheses and conformational analyses of a range of 9-substituted 2, 3, 6, 7-tetramethyldecahydroanthracenes are discussed.

Details

ISSN :
09317597
Volume :
20
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........89e9c8ca509837145dcd64d03bbdf141