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Synthesis and enantiomer recognition of crown ethers containing cyclohexane-1,2-diol derivatives as the chiral centre and enzymatic resolution of the chiral subunits
- Source :
- Journal of the Chemical Society, Perkin Transactions 1. :957
- Publication Year :
- 1991
- Publisher :
- Royal Society of Chemistry (RSC), 1991.
-
Abstract
- The cyclohexane-1,2-diol derivatives 1 and 4 of high optical purity have been prepared by enantioselective hydrolysis of their acetates (±)-2 and (±)-5 using pig liver esterase. The enantiomer recognition behaviour of the chiral crown ethers 11, 14, 15 and 16 containing the cyclohexane-1,2-diol derivatives as a chiral subunit has also been examined.
Details
- ISSN :
- 13645463 and 0300922X
- Database :
- OpenAIRE
- Journal :
- Journal of the Chemical Society, Perkin Transactions 1
- Accession number :
- edsair.doi...........899155d5770f4871e559e4c49f2e76a0