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A case study of the MAC (masked acyl cyanide) oxyhomologation of N,N-dibenzyl-<scp>l</scp>-phenylalaninal with anti diastereoselectivity: preparation of (2S,3S)-allophenylnorstatin esters

Authors :
Xuefeng He
Marie Buchotte
Régis Guillot
Sandrine Deloisy
David J. Aitken
Source :
Organic & Biomolecular Chemistry. 20:1769-1781
Publication Year :
2022
Publisher :
Royal Society of Chemistry (RSC), 2022.

Abstract

The three-component reaction proceeds with unhindered alcohols in good yield and high anti diastereoselectivity to give protected ester derivatives of (2S,3S)-allophenylnorstatin and provides an expedient access to the amino acid itself.

Details

ISSN :
14770539 and 14770520
Volume :
20
Database :
OpenAIRE
Journal :
Organic & Biomolecular Chemistry
Accession number :
edsair.doi...........8980e21b7c7fddbee7e8d4c0a5f51c90
Full Text :
https://doi.org/10.1039/d1ob02411f