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Study on the reaction of CO coupling to oxalate

Authors :
Genhui Xu
Jingang Fang
Baowei Wang
Zhenhua Li
Source :
Reaction Kinetics and Catalysis Letters. 80:293-301
Publication Year :
2003
Publisher :
Springer Science and Business Media LLC, 2003.

Abstract

The synthesis of diethyl oxalate from ethyl nitrite and carbon monoxide in gaseous phase has been studied at atmospheric pressure. Kinetics of coupling - regeneration reaction has been determined and the optimization of the reaction has been simulated. The influences of gas impurities has also been studied. Scale-up circulating shows that the concentrate and selectivity were stable in the product and the process is suitable for industrial production.

Subjects

Subjects :
Atmospheric pressure
Ethyl nitrite
Inorganic chemistry
Kinetics
Catalysis
Oxalate
chemistry.chemical_compound
chemistry
Impurity
Astrophysics::Earth and Planetary Astrophysics
Physical and Theoretical Chemistry
Selectivity
Physics::Atmospheric and Oceanic Physics
Carbon monoxide

Details

ISSN :
01331736
Volume :
80
Database :
OpenAIRE
Journal :
Reaction Kinetics and Catalysis Letters
Accession number :
edsair.doi...........892e4f73bfbb905a873d89b89cdb4456
Full Text :
https://doi.org/10.1023/b:reac.0000006138.57139.16
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