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A Series of Iron Nitrosyl Complexes {Fe–NO}6–9 and a Fleeting {Fe–NO}10 Intermediate en Route to a Metalacyclic Iron Nitrosoalkane

Authors :
Frank W. Heinemann
Karsten Meyer
Martin Keilwerth
Eckhard Bill
Huayi Fang
Johannes Hohenberger
Andreas Scheurer
Joerg Sutter
Frank Neese
Shengfa Ye
Source :
Journal of the American Chemical Society. 141:17217-17235
Publication Year :
2019
Publisher :
American Chemical Society (ACS), 2019.

Abstract

Iron–nitrosyls have fascinated chemists for a long time due to the noninnocent nature of the NO ligand that can exist in up to five different oxidation and spin states. Coordination to an open-shel...

Details

ISSN :
15205126 and 00027863
Volume :
141
Database :
OpenAIRE
Journal :
Journal of the American Chemical Society
Accession number :
edsair.doi...........87f58b95b42e20a8f16855b783428a6f
Full Text :
https://doi.org/10.1021/jacs.9b08053