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2-Carbamoylaziridine (Leakadine): diastereoselective transformations and stereoelectronic effect*
- Source :
- Chemistry of Heterocyclic Compounds. 48:869-874
- Publication Year :
- 2012
- Publisher :
- Springer Science and Business Media LLC, 2012.
-
Abstract
- Diastereoselective transformations of Leakadine were discovered: dimerization during melting or heating in CHCl3 with the formation of one diastereomer. The obtained dimer reacts with methyl isocyanate under mild conditions with the formation of an N-methylcarbamoyl derivative – also in the form of one diastereomer. In the diastereoselective reaction of Leakadine with dimethyl formamide dimethyl acetal, 2-dimethylamino-1,3-diazabicyclo[3.1.0]hexan-4-one was obtained. The reaction of Leakadine with perfluoroisobutylene was studied.
Details
- ISSN :
- 15738353 and 00093122
- Volume :
- 48
- Database :
- OpenAIRE
- Journal :
- Chemistry of Heterocyclic Compounds
- Accession number :
- edsair.doi...........87b8be7bebb703ee4c2cbce26c5dc7d1
- Full Text :
- https://doi.org/10.1007/s10593-012-1068-1