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Kinetics of an Inverse Diene Synthesis in the Pure Liquid State

Authors :
A. Wassermann
B. S. Khambata
Source :
Nature. 138:368-369
Publication Year :
1936
Publisher :
Springer Science and Business Media LLC, 1936.

Abstract

THE decomposition of dicyclopentadiene into cyclopentadiene is an inverse diene synthesis. It was found previously1 that in paraffin solution the reaction is monomolecular and that the rate constant is given by k = 6.0 × 1012 e34000/RT sec.1.

Details

ISSN :
14764687 and 00280836
Volume :
138
Database :
OpenAIRE
Journal :
Nature
Accession number :
edsair.doi...........879c300ebbfbeb3a40bb2cf07a90fb7e
Full Text :
https://doi.org/10.1038/138368c0