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Structures and properties of isomeric cyclodiphosph(III)azanes; X-ray crystal and molecular structure of 2,4-dipiperidino-1,3-di-t-butylcyclodiphosph(III)azane
- Source :
- Journal of the Chemical Society, Chemical Communications. :372
- Publication Year :
- 1978
- Publisher :
- Royal Society of Chemistry (RSC), 1978.
-
Abstract
- Marked differences have been found in the nucleophilic reactivity, basicity, and photoelectron spectra of geometrical isomers of the cyclodiphosph(III)azanes, (XPNBut)2(X = NMe2 or OMe), whose structures were assigned by reference to the crystal structure of cis-(C5H10N·PNBut)2.
Details
- ISSN :
- 00224936
- Database :
- OpenAIRE
- Journal :
- Journal of the Chemical Society, Chemical Communications
- Accession number :
- edsair.doi...........875b15f8506711c0595423d5330bb8b0