Stereoselective 1,4 bromination of semibullvalene and tri-n-butyltin hydride reduction of the dibromide

Authors :: Leo A. Paquette
Bruce A. Parkinson
Gary H. Birnberg
Jon Clardy
Source :: Journal of the Chemical Society, Chemical Communications. :129
Publication Year :: 1973
Publisher :: Royal Society of Chemistry (RSC), 1973.
Abstract: Bromination of semibullvalene proceeds with stereoselective cis,exo-1,4-addition in contrast to bullvalene where kinetically controlled trans-1,4-addition occurs.

Subjects :: chemistry.chemical_compound
Chemistry
Tri-n-butyltin hydride
Molecular Medicine
Halogenation
Organic chemistry
Stereoselectivity
Bullvalene

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