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Conformationally restricted analogues of methionine: Synthesis of chiral 3-Amino-5-methylthio-2-piperidones

Authors :
M. Angels Estiarte
Mario Rubiralta
Anna Colell
JoséC. Fernández-Checa
Ricardo Rodríguez
Anna Diez
Carmen García-Ruiz
Source :
Tetrahedron. 52:7727-7736
Publication Year :
1996
Publisher :
Elsevier BV, 1996.

Abstract

(αR, 3RS, 5S)-3-Amino-N-(2-hydroxy-1-phenylethyl)-5-methylthio-2-piperidones1 have been synthesized from enamide 2 by subsequent free radical addition of methanothiol on position 5 and amination of 3-position.

Details

ISSN :
00404020
Volume :
52
Database :
OpenAIRE
Journal :
Tetrahedron
Accession number :
edsair.doi...........864dc771bcdec8c834b9964ddc4044ee
Full Text :
https://doi.org/10.1016/s0040-4020(96)00340-7