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Surface morphology studies of multiblock and starblock copolymers of poly(.alpha.-methylstyrene) and poly(dimethylsiloxane)
- Source :
- Macromolecules. 26:3778-3783
- Publication Year :
- 1993
- Publisher :
- American Chemical Society (ACS), 1993.
-
Abstract
- Surface morphology and compositions of multiblock and starblock copolymers of poly(a-methyl styrene) (PMS) and poly(dimethyl siloxane) (PDMS) were investigated by cross-sectional transmission electron microscopy, angle- and energy-dependent ESCA, and infrared spectroscopy. The extent of surface segregation of PDMS was determined for multiblock and starblock copolymers to depth of 210{angstrom}. No surface excess was with high PDMS bulk concentrations (60 wt%) have a highly oriented lamellar morphology in the near air surface region, and the topmost air surface region (27 {angstrom}) is exclusively composed of PDMS. The PMS-PDMS block copolymers with lower PDMS bulk concentrations (40 wt%) have lesser or no domain orientation and the surface region includes detectable PMS.
- Subjects :
- Materials science
Polymers and Plastics
Organic Chemistry
technology, industry, and agriculture
Infrared spectroscopy
macromolecular substances
alpha-Methylstyrene
Styrene
Inorganic Chemistry
symbols.namesake
chemistry.chemical_compound
Gibbs isotherm
chemistry
Chemical engineering
Transmission electron microscopy
Polymer chemistry
Materials Chemistry
symbols
Copolymer
Lamellar structure
Polystyrene
Subjects
Details
- ISSN :
- 15205835 and 00249297
- Volume :
- 26
- Database :
- OpenAIRE
- Journal :
- Macromolecules
- Accession number :
- edsair.doi...........85c74dca95d458fcb1851a0100c7304c