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An Efficient Palladium-NHC (NHC=N-Heterocyclic Carbene) and Aryl Amination Pre-Catalyst: [Pd(IPr*)(cinnamyl)Cl]
- Source :
- Advanced Synthesis & Catalysis. 354:1897-1901
- Publication Year :
- 2012
- Publisher :
- Wiley, 2012.
-
Abstract
- The well-defined [Pd(IPr*)(cinnamyl)Cl] complex is reported as one of the best N-heterocyclic carbene (NHC)-based pre-catalysts for the Buchwald–Hartwig amination reaction. This catalytic system displays high efficiency for the coupling of numerous (hetero)aryl chlorides, with a wide range of amines, at room temperature or at extremely low catalyst loading (as low as 0.025 mol%).
Details
- ISSN :
- 16154150
- Volume :
- 354
- Database :
- OpenAIRE
- Journal :
- Advanced Synthesis & Catalysis
- Accession number :
- edsair.doi...........856dbfbc6ad5037fc62eb79ee94e6901