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Rationalizing hydrogen bond solvation with Kamlet–Taft LSER and molecular torsion balances

Authors :
Bright U. Emenike
Arzu Sevimler
Amiel Farshadmand
Armando J. Roman
Source :
Physical Chemistry Chemical Physics.
Publication Year :
2023
Publisher :
Royal Society of Chemistry (RSC), 2023.

Abstract

The Kamlet–Taft solvation model partitioned experimental solvent effects on intramolecular hydrogen bonding into electrostatic and dispersion terms, revealing their relative contributions to the folding preference of a molecular torsion balance.

Details

ISSN :
14639084 and 14639076
Database :
OpenAIRE
Journal :
Physical Chemistry Chemical Physics
Accession number :
edsair.doi...........8539f259c83f309490ab9a4c8af661f5