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Catalytic dehydrocoupling of methylamine borane using Yamashita's [Ir(PBP)] boryl complex – characterisation of a novel highly fluxional Ir tetrahydride

Authors :
David Decker
Hans-Joachim Drexler
Wolfgang Baumann
Fabian Reiß
Torsten Beweries
Source :
New Journal of Chemistry. 46:22314-22321
Publication Year :
2022
Publisher :
Royal Society of Chemistry (RSC), 2022.

Abstract

Catalytic dehydropolymerisation of methylamine borane using the boryl pincer complex [(PBP)Ir(H)(Cl)]/NaOtBu proceeds via an unusual highly fluxional Ir tetrahydride.

Details

ISSN :
13699261 and 11440546
Volume :
46
Database :
OpenAIRE
Journal :
New Journal of Chemistry
Accession number :
edsair.doi...........84cac63e4ef09c78d29499a5ee42bd54
Full Text :
https://doi.org/10.1039/d2nj04914g