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An investigation into the Brønsted acidity of the perfluorinated alkoxy silanes {(F3C)3CO}3SiH and {(F6C5)3CO}2Si(Cl)H
- Source :
- Dalton Transactions. 52:5918-5925
- Publication Year :
- 2023
- Publisher :
- Royal Society of Chemistry (RSC), 2023.
-
Abstract
- The Si–H bond in {(F3C)3CO}3SiH is exceptionally strong and short; yet the acidity is comparable to common organic acids. This apparent contradiction will be discussed with the aid of contemporary DFT methods.
- Subjects :
- Inorganic Chemistry
Subjects
Details
- ISSN :
- 14779234 and 14779226
- Volume :
- 52
- Database :
- OpenAIRE
- Journal :
- Dalton Transactions
- Accession number :
- edsair.doi...........848f66c0107c12f3b0a96cb983993bb7
- Full Text :
- https://doi.org/10.1039/d3dt00299c