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The Cl to NCl branching ratio in 248-nm photolysis of chlorine azide
- Source :
- Chemical Physics Letters. 391:334-337
- Publication Year :
- 2004
- Publisher :
- Elsevier BV, 2004.
-
Abstract
- The primary reaction products from 248-nm chlorine azide photolysis are identified in a collision-free experiment. In contrast to all previous reports, the radical channel producing Cl + N3 (95 � 3%) is seen to dominate the photochemistry. The molecular channel producing NCl + N2 (5 � 3%) was also observed. 2004 Elsevier B.V. All rights reserved.
Details
- ISSN :
- 00092614
- Volume :
- 391
- Database :
- OpenAIRE
- Journal :
- Chemical Physics Letters
- Accession number :
- edsair.doi...........846fa7c929448008e87c9ee38af17b71