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ChemInform Abstract: A New Model for Coenzyme B12

Authors :
R. J. van Delft
M. W. G. De Bolster
H. de Koning
Y. Van Den Winkel
B. van Arkel
G. W. Klumpp
Sijbe Balt
J. L. Van Der Baan
Source :
ChemInform. 19
Publication Year :
1988
Publisher :
Wiley, 1988.

Abstract

A new cobaloxime-type model for coenzyme B12 has been synthesized. For this model strong steric repulsion between its dioxymethylene bridge and (one of) the axial ligands on cobalt presages enhanced rates of axial ligand exchange.

Subjects

Subjects :
Crystallography
Chemistry
Ligand
chemistry.chemical_element
General Medicine
Coenzyme B12
Bridge (interpersonal)
Cobalt
Steric repulsion

Details

ISSN :
09317597
Volume :
19
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........846d0896eede687715ecc90c77702976
Full Text :
https://doi.org/10.1002/chin.198823290
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