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A Convenient Synthesis of Chiral, Non-Racemic [4aS,8aR]-5,5,8a-Trimethyl Octahydro-2,2-(1,3-Dioxolane)-Naphthalene
- Source :
- Synthetic Communications. 30:1371-1378
- Publication Year :
- 2000
- Publisher :
- Informa UK Limited, 2000.
-
Abstract
- (-)-(4aS,8aR)-5,5-8a-trimethyl-trans-decaline 1 was prepared in a stereoespecific synthesis of 4 steps and 38% yield. The key-step involves an asymmetric Robinson annulation via Michael addition of chiral imine.
Details
- ISSN :
- 15322432 and 00397911
- Volume :
- 30
- Database :
- OpenAIRE
- Journal :
- Synthetic Communications
- Accession number :
- edsair.doi...........83f2e71091248d40847f5dd03182ac55