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Efficient Synthesis of Trimethylsilyl Pseudohalides Catalyzed by PEG400/ZnI2under Ultrasound Irradiation

Authors :
Wang Sufang
Wang Shaobing
Xu Yongshen
Source :
Synthetic Communications. 35:1271-1276
Publication Year :
2005
Publisher :
Informa UK Limited, 2005.

Abstract

Trimethylsilyl pseudohalides Me3SiX, where X = NCS, NCO, or CN, were readily prepared conveniently in desirable yields by the reaction of Me3SiCl with NaX or KX catalyzed by PEG400 and zinc iodide under ultrasound irradiation.

Details

ISSN :
15322432 and 00397911
Volume :
35
Database :
OpenAIRE
Journal :
Synthetic Communications
Accession number :
edsair.doi...........8348c6bc1d33208eefcb639d00ff81e5
Full Text :
https://doi.org/10.1081/scc-200054856