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Electrochemical uptake/release of lithium in GaNb11O29 nanowires as anode material for rechargeable lithium ion battery
- Source :
- Ceramics International. 46:20537-20544
- Publication Year :
- 2020
- Publisher :
- Elsevier BV, 2020.
-
Abstract
- Nowadays, it is of great urgency to research for appropriate materials to construct high-performance lithium-ion batteries (LIBs) because of the growth of social demand. Among them, niobium type metal oxides are potential candidates for anode materials. Here, we propose GaNb11O29 with shear-ReO3 crystal structure as anode material. It is an intercalation-type material with high theoretical capacity and safe working voltage. In this work, GaNb11O29 nanowires are synthesized by electrospinning. The nanostructure design can effectively improve lithium storage behavior. Accordingly, GaNb11O29 nanowires provide a high reversible capacity (233.4 mAh g-1 at 100 mA g-1), outstanding rate capability (168.8 mAh g-1 at 700 mA g-1) and superior long-term stability (0.031% capacity loss per cycle after 500 cycles). Furthermore, the kinetic analysis confirms the pseudocapacitive contribution during cycling, which contributes to the rapid Li-storage. In addition, in-situ XRD characterization is conducted to further unveil the Li-storage mechanism in lithiation/delithiation processes. This work suggests that GaNb11O29 nanowires are potential anode material for rechargeable batteries, which enriches the choice for high-performance LIBs.
- Subjects :
- 010302 applied physics
Nanostructure
Materials science
Process Chemistry and Technology
Nanowire
chemistry.chemical_element
Nanotechnology
02 engineering and technology
021001 nanoscience & nanotechnology
Electrochemistry
01 natural sciences
Lithium-ion battery
Electrospinning
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Anode
chemistry
0103 physical sciences
Materials Chemistry
Ceramics and Composites
Lithium
0210 nano-technology
Capacity loss
Subjects
Details
- ISSN :
- 02728842
- Volume :
- 46
- Database :
- OpenAIRE
- Journal :
- Ceramics International
- Accession number :
- edsair.doi...........82cf273045d75f5c63230dcdab36ab6a