Diastereoselective Epoxidation ofN-Enoylsultams with Different Chiral Sultams as Auxiliaries

Authors :: Yong-Kang Chen
Viktor O. Rogatchov
Shu-Jia Zhang
Wei-Yang Huang
Peter Metz
Hui-Ming Li
Source :: Chinese Journal of Chemistry. 24:681-688
Publication Year :: 2006
Publisher :: Wiley, 2006.
Abstract: Asymmetric epoxidation of N-enoylsultams (1, 3–15) incorporating a variety of chiral sultams as the chiral induction elements with UHP/TFAA has been studied. Both diastereomeric isomers of epoxides (2, 16–28) were obtained in high yield and moderate to high optical purity.

Subjects :: Chiral auxiliary
chemistry.chemical_compound
chemistry
Yield (chemistry)
Diastereomer
Organic chemistry
General Chemistry
Enantiomeric excess
Chiral induction

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