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Alkoxo- and carboxylato-bridged hexanuclear copper(II) complex: Synthesis, structure and magnetic properties

Authors :
Javid Khan
Muhammad Nadeem Akhtar
Murad A. AlDamen
Yan-Cong Chen
Ming-Liang Tong
Masaaki Sadakiyo
Source :
Inorganic Chemistry Communications. 83:49-51
Publication Year :
2017
Publisher :
Elsevier BV, 2017.

Abstract

Reaction of copper(II) nitrate trihydrate with N,N-dimethylethanolamine (dmea) and pivalic acid in methanol led to the hexanuclear copper(II) complex Cu6(η1:μ2-C4H10NO)4(η1:η1:μ2-C5H9O2)4(η1:μ1-C5H9O2)2(μ3-OH)2 (1). The crystal structure of 1 indicates that hexametallic centers are bridged by the μ3-alkoxo, dmea oxygens, and the μ2-dicarboxylato oxygen atoms of pivalate ions. Furthermore, in the asymmetric unit, three types of copper ions have been found labeled as Cu1, Cu2 and Cu3. The Cu2 takes a distorted octahedral shape, whereas Cu1 and Cu3 adopt square pyramidal geometries. The complex 1 shows strong antiferromagnetic interactions through the oxo groups within the dimeric units (J = − 82.6 to − 25.8 cm− 1) and weak antiferromagnetic couplings between the dimers (J = − 10.9 and 0.8 cm− 1).

Details

ISSN :
13877003
Volume :
83
Database :
OpenAIRE
Journal :
Inorganic Chemistry Communications
Accession number :
edsair.doi...........82a1523b44579990fb2c88bdf9e1ea5a
Full Text :
https://doi.org/10.1016/j.inoche.2017.06.012