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Alkoxo- and carboxylato-bridged hexanuclear copper(II) complex: Synthesis, structure and magnetic properties
- Source :
- Inorganic Chemistry Communications. 83:49-51
- Publication Year :
- 2017
- Publisher :
- Elsevier BV, 2017.
-
Abstract
- Reaction of copper(II) nitrate trihydrate with N,N-dimethylethanolamine (dmea) and pivalic acid in methanol led to the hexanuclear copper(II) complex Cu6(η1:μ2-C4H10NO)4(η1:η1:μ2-C5H9O2)4(η1:μ1-C5H9O2)2(μ3-OH)2 (1). The crystal structure of 1 indicates that hexametallic centers are bridged by the μ3-alkoxo, dmea oxygens, and the μ2-dicarboxylato oxygen atoms of pivalate ions. Furthermore, in the asymmetric unit, three types of copper ions have been found labeled as Cu1, Cu2 and Cu3. The Cu2 takes a distorted octahedral shape, whereas Cu1 and Cu3 adopt square pyramidal geometries. The complex 1 shows strong antiferromagnetic interactions through the oxo groups within the dimeric units (J = − 82.6 to − 25.8 cm− 1) and weak antiferromagnetic couplings between the dimers (J = − 10.9 and 0.8 cm− 1).
- Subjects :
- Pivalic acid
010405 organic chemistry
Inorganic chemistry
chemistry.chemical_element
Crystal structure
010402 general chemistry
01 natural sciences
Copper
Square pyramidal molecular geometry
0104 chemical sciences
Ion
Inorganic Chemistry
chemistry.chemical_compound
Crystallography
chemistry
Octahedron
Materials Chemistry
Antiferromagnetism
Methanol
Physical and Theoretical Chemistry
Subjects
Details
- ISSN :
- 13877003
- Volume :
- 83
- Database :
- OpenAIRE
- Journal :
- Inorganic Chemistry Communications
- Accession number :
- edsair.doi...........82a1523b44579990fb2c88bdf9e1ea5a
- Full Text :
- https://doi.org/10.1016/j.inoche.2017.06.012