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Control of Excited-State Proton-Coupled Electron Transfer by Ultrafast Pump-Push-Probe Spectroscopy in Heptazine-Phenol Complexes: Implications for Photochemical Water Oxidation

Authors :
Andrzej L. Sobolewski
Wolfgang Domcke
Johannes Ehrmaier
Emily J. Rabe
Kathryn L. Corp
Xiang Huang
Mitchell E. Kaiser
Cody W. Schlenker
Source :
The Journal of Physical Chemistry C. 124:9151-9160
Publication Year :
2020
Publisher :
American Chemical Society (ACS), 2020.

Abstract

We demonstrate chemical tuning and laser-driven control of intermolecular H atom abstraction from protic solvent molecules. Using multipulse ultrafast pump-push-probe transient absorption (TA) spec...

Details

ISSN :
19327455 and 19327447
Volume :
124
Database :
OpenAIRE
Journal :
The Journal of Physical Chemistry C
Accession number :
edsair.doi...........826a4b20ebc07016fc395af0071fceaf
Full Text :
https://doi.org/10.1021/acs.jpcc.0c00415