Back to Search
Start Over
Crystal Structures and Intercalation Reactions of Three‐Dimensional Coordination Polymers [M(H 2 O) 2 ] 2 [Mo(CN) 8 ]·4H 2 O (M = Co, Mn)
- Source :
- European Journal of Inorganic Chemistry. 2003:1866-1872
- Publication Year :
- 2003
- Publisher :
- Wiley, 2003.
-
Abstract
- Two coordination polymers [MII(H2O)2]2[MoIV(CN)8]·4H2O [MII = Co (1), Mn (2)] were prepared as monocrystals and structurally characterised. These compounds crystallise in the tetragonal systems I4/m (1) and I4/mcm (2) and form three-dimensional networks containing channels occupied by two types of water molecules, i.e. coordinated to MII and crystallised ones. The dehydration of these materials occurs topochemically to give [MII(H2O)]2[MoIV(CN)8] compounds having an open metal coordination site on the MII ions that may be accessible to coordination by other species and serve as a reaction site. The intercalation of water, ammonia and amines has been studied. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
Details
- ISSN :
- 10990682 and 14341948
- Volume :
- 2003
- Database :
- OpenAIRE
- Journal :
- European Journal of Inorganic Chemistry
- Accession number :
- edsair.doi...........82532efddf44b920fa7ff3625299abe6