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ChemInform Abstract: One-Pot Synthesis of Allylic Sulfones, Ketosulfones, and Triflyl Allylic Alcohols from Domino Reactions of Allylic Alcohols with Sulfinic Acid under Metal-Free Conditions

Authors :
Xiao-Ping Xu
Hua Meng
Xue-Qiang Chu
Shun-Jun Ji
Source :
ChemInform. 46
Publication Year :
2015
Publisher :
Wiley, 2015.

Abstract

Sulfonylation of alcohols (I) provides allylic sulfones, which undergo an oxidative functionalization to yield ketosulfones (IV) and (X) or triflyl allylic alcohols (VII).

Details

ISSN :
09317597
Volume :
46
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........81bf6a05d924a3dba7ca3de1208386ba
Full Text :
https://doi.org/10.1002/chin.201550089