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Rare-Earth Metal Boroxide with Formal Triple Metal–Oxygen Orbital Interaction: Synthesis from B(C 6 F 5 ) 3 ·H 2 O and Radical-Anion Ligated Rare-Earth Metal Amides

Authors :
Han-Shi Hu
Haihan Yan
Botao Wu
Wen-Xiong Zhang
Xiao-Kun Zhao
Zhenfeng Xi
Chao Yu
Junnian Wei
Source :
CCS Chemistry. 3:2772-2781
Publication Year :
2021
Publisher :
Chinese Chemical Society, 2021.

Abstract

Rare-earth metal boroxides are not only rare and of great synthetic challenge but also important theoretically due to their unrevealed bonding characteristics. In this paper, we report the synthesi...

Details

ISSN :
20965745
Volume :
3
Database :
OpenAIRE
Journal :
CCS Chemistry
Accession number :
edsair.doi...........8184b9e0552108f2c108ab195c59dc65
Full Text :
https://doi.org/10.31635/ccschem.020.202000587